Electronic Properties of FC(O)SCH2CH3. A Combined Helium(I) Photoelectron Spectroscopy and Synchrotron Radiation Study

L. R. PIRANI, M. F. ERBEN, M. GERONÉS, R. M. ROMANO, R. L. CAVASSO FILHO,CHUNPING MA, M. GE Y C.O. DELLA VÉDOVA

JOURNAL OF PHYSICAL CHEMISTRY A

AMER CHEMICAL SOC

Lugar: Washington; Año: 2014 vol. 118 p. 5950 - 5960

1089-5639

The valence electronic properties of FC(O)SCH2CH3, were investigated by means of He(I) photoelectron spectroscopy in conjunction with the analysis of the photofragmentation products determined by PEPICO by using synchrotron radiation in the 11.1-21.6 eV photon energy range. Moreover, S 2p and S 2s absorption edges have been examined by measuring the total ion yield spectra in the 160-240 eV region using variable synchrotron radiation. The dynamic of ionic fragmentation following the Auger electronic decay has been evaluated with the help of the PEPIPICO technique.