PERSONAL DE APOYO
DURAN Alejandra
artículos
Título:
Membrane catalyst for partial hydrogenation of 1,3-butadiene: catalytic properties of palladium nanoclusters synthetized within diblock copolymer films
Autor/es:
DURÁN ALEJANDRA; CIEBIEN J.; COHEN R.
Revista:
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
Editorial:
ELSEVIER SCIENCE SA
Referencias:
Lugar: Amsterdam; Año: 1999 vol. 7 p. 45 - 50
ISSN:
0921-5093
Resumen:
Palladium nanoclusters were synthetized within microphase-separated diblock copolymer films. The nanocomposite films were active and selective catalysis for the gas phase hydrogenation of 1,3-butadiene. Selectivity for butenes was improved by lowering the hydrogen partial pressure, and lower temperature favored formation of 1-butene over 2-butenes.
