A combined experimental and DFT study on the zero valent iron/reduced graphene oxide doped QCM sensor for determination of trace concentrations of As using a Flow-batch system

GUTIÉRREZ, JULIÁN; ROBEIN, YAEL N.; JUAN, JULIÁN; DI NEZIO, MARÍA S.; PISTONESI, CAROLINA; GONZÁLEZ, ESTELA A.; SANTOS, RODRIGO; PISTONESI, MARCELO F.

SENSORS AND ACTUATORS B-CHEMICAL

ELSEVIER SCIENCE SA

Año: 2024 vol. 404

0925-4005

A sensor based on a gold Quartz Crystal Microbalance (QCM) modified with nanoscale zero-valent iron nanoparticles (nZVI) anchored to reduced graphene oxide (rGO) was developed. An automated measurement microsystem was employed using QCM (modified and unmodified) as an arsine detector device. The QCM measurements of frequency changes are associated with total As concentration (III/V) in the samples. The gold surface QCM modification with nZVI/rGO improved the sensitivity in total As determination. The limit of detection (LOD) was 0.0062 ng mL−1 for QCM-Au/nZVI/rGO, 100 times higher than the unmodified QCM-Au sensor. Moreover, studies of adsorption energy and electron density of As with QCM-Au/nZVI/rGO and QCM-Au systems were performed. For this purpose, Density Functional Theory (DFT) methodology was used employing arsine adsorption on magnetite nanoparticles supported on graphene, and also on Au as models. This theoretical-experimental research allows us to acquire knowledge of the interaction of Au/nZVI/rGO with As and confirms the experimental results.