INVESTIGADORES
VEGA Daniel Alberto
congresos y reuniones científicas
Título:
Bulk and Solution Properties of Model PS-b-PDMS Copolymers
Autor/es:
NINAGO MD; SATTI AJ; DA VEGA; EM VALLES; VILLAR MA; CIOLINO A
Lugar:
Blankenberge
Reunión:
Encuentro; BPG Annual Meeting 2011; 2011
Institución organizadora:
Belgian Polymer Group
Resumen:
True model linear poly(styrene-b-dimethylsiloxane) PS-b-PDMS copolymers were synthesized by using sequential addition of monomers and anionic polymerization (high-vacuum techniques). The model diblock copolymers obtained were analyzed by using different techniques, such as size-exclusion chromatography, NMR, Fourier transform infrared spectroscopy, small angle X-rays scattering (SAXS), and wide angle X-rays scattering (WAXS). The PS-b-PDMS copolymers obtained showed narrow molar mass distribution and variable PDMS content, ranging from 2 up to 55 wt %.