Effect of the crosslinking agent on porous networks formation of HEMA based copolymers

CESAR GOMEZ; CECILIA ALVAREZ; MIRIAM STRUMIA

POLYMER

Elsevier

Año: 2004 vol. 45 p. 6189 - 6194

0032-3861

New copolymers of ethylene glycol dimethacrylate/2-hydroxyethyl methacrylate [poly(EGDMA-co-HEMA)],2,20,200-nitrilotriethyl triacrylate/2-hydroxyethyl methacrylate [poly(NTETA-co-HEMA)] and pentaerythritol tetraacrylate/2-hydroxyethyl methacrylate [poly- (PETA-co-HEMA)] were obtained by suspension polymerization at 70 or 85 8C, using cyclohexane (Cyc) as porogen. In this work, the influence of the crosslinking agent (di, tri, or tetravinyl monomer) on the morphology of the polymeric networks was investigated. Swelling studies, Fourier Transform Infrared (FTIR) and mercury intrusion porosimetry, demonstrated that when both the vinyl groups number and molecular chain length between double bonds of the crosslinking agent decreased, networks with high porosity and crosslinking degree were generated.