Hybrid Dendritic-Linear Copolymers: Synthesis and Reactivity

PABLO FROIMOWICZ, JULIETA PAEZ, ALESSANDRO GANDINI, NACEUR BELGACEM, MIRIAM STRUMIA.

Macromolecular Symposia

Wiley

Lugar: USA; Año: 2006 vol. 245- p. 51 - 60

Summary: A novel hybrid aromatic dendritic-linear copolymer from Jeffamine1 was synthesized by an adaptation of Kakimoto’s procedure. Comparative studies of reactivity between aromatic and aliphatic hybrid dendritic-linear copolymers were carried out, through which the best reactivity and the derivatizing capacity of this novel copolymer were clearly demonstrated for the aromatic hybrid dendritic-linear copolymer. Schiff’s base formation by reaction with a chromophore (MFVF) gave hybrid copolymer interesting crosslinkable properties.A novel hybrid aromatic dendritic-linear copolymer from Jeffamine1 was synthesized by an adaptation of Kakimoto’s procedure. Comparative studies of reactivity between aromatic and aliphatic hybrid dendritic-linear copolymers were carried out, through which the best reactivity and the derivatizing capacity of this novel copolymer were clearly demonstrated for the aromatic hybrid dendritic-linear copolymer. Schiff’s base formation by reaction with a chromophore (MFVF) gave hybrid copolymer interesting crosslinkable properties.MFVF) gave hybrid copolymer interesting crosslinkable properties. Keywords: crosslinkable properties; dendritic Jeffamine; hybrid dendritic-crosslinkable properties; dendritic Jeffamine; hybrid dendritic-