Finite Size Scaling for Critical Conditions for Stable Dipole-Bound Anions

PABLO SERRA; SABRE KAIS

CHEMICAL PHYSICS LETTERS

ELSEVIER SCIENCE BV

Lugar: Amsterdam; Año: 2003 vol. 372 p. 205 - 209

0009-2614

We present a finite-size scaling approach for the calculations of the critical parameters for binding an electron to an electric dipole field. This approach gives very accurate results for the critical parameters by using a systematic expansion in a finite basis set. The approach is general and could be used to obtain the critical conditions for stable dipole-bound dianions.