INVESTIGADORES
RICCARDO Jose Luis
artículos
Título:
Fractional Statistical Theory of Adsorption of Polyatomics
Autor/es:
J.L. RICCARDO; A.J. RAMIREZ PASTOR; F. ROMÁ
Revista:
PHYSICAL REVIEW LETTERS
Editorial:
American Institute of Physics
Referencias:
Año: 2004 vol. 93 p. 1861011 - 1861014
ISSN:
0031-9007
Resumen:
A new theoretical description of fractional statistical theory of adsorption (FSTA) phenomena ispresented based on Haldanes statistics. Thermodynamic functions for adsorption of polyatomics areanalytically developed. The entropy is characterized by an exclusion parameter g, which relates to theconfiguration of the admolecules and surface geometry. FSTA provides a simple framework to address alarge class of complex adsorption systems. Comparisons of theoretical adsorption isotherms withexperiments and simulations indicate that adsorption configuration and adsorption energy can accurately be assessed from this theory.
