Sulfonic functionalized SBA-15 catalysts in the gas phase glycerol dehydration. Thermal stability and catalyst deactivation

B. DALLA COSTA; LEGNOVERDE, S.; LAGO, C.D.; DECOLATTI, H.; QUERINI, C.A.

MICROPOROUS AND MESOPOROUS MATERIALS

ELSEVIER SCIENCE BV

Lugar: Amsterdam; Año: 2016

1387-1811

The catalytic conversion of glycerol to acrolein was studied using sulfonicfunctionalized mesoporous silica SBA-15. The catalysts were prepared by the cocondensationmethod, conducting the silica synthesis and functionalization of its surfacewith thiol-propyl groups in the same stage. In a next step, the oxidation of thiol groupsto sulfonic groups was made varying the concentration of H2O2 in order to obtaincatalysts with different levels of acidity on the surface. The solids were characterized byBET, SEM, FTIR, XPS, and potentiometric titration with n-butilamine. The thermalstability was analyzed by thermogravimetry (TGA) and temperature-programmeddesorption (TPD). The reaction tests were performed at different temperatures between275 ºC and 350 ºC, and under feed flow conditions that allowed the study of thedeactivation phenomena by coke deposition. The best temperature in order to maximizethe acrolein yield was 300 ºC. Higher temperatures led to a rapid deactivation by acombined effect of coke deposition and decomposition of functional groups.