Glass sintering with concurrent crystallization

PRADO, M. O.; ZANOTTO, EDGAR DUTRA

COMPTES RENDUS CHIMIE

ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER

Lugar: Paris; Año: 2002 vol. 5 p. 773 - 786

1631-0748

We critically review and discuss the main glass-sintering models: Frenkel, Mackenzie?Shuttleworth, Scherer and the recently developed Clustersmodel, and focus on the problem of sintering with concurrent crystallization. TheClustersmodel is tested under various practical conditions. Isothermal tests are carried out on a widely polydispersed alumino-borosilicate (ABS) glass having jagged particles, which is stable against devitrification, and on a soda?lime?silica (SLS) glass with a narrow spherical particle distribution, which crystallizes easily. The algorithm for non-isothermal processes is also tested with twodistinct systems: the same ABS glass and a narrow-sized cordierite glass, which is  devitrification-prone. In addition to physical parameters such as viscosity, surface tension, particle-size distribution, crystal growth rate and number of nucleation sites, microscopic-particle-packing data are introduced into the model and it is demonstrated that the evolution of both density and pore size distribution can be reasonably predicted. All the results are discussed taking into account the assumptions made in the derivations and other complicating factors, such as irregular particle shape, compositional shifts due to crystallization, tempera-ture gradients and degassing during sintering. Finally, we discuss the physical and processing parameters that determine whether sintering will be favorable over crystallization. We demonstrate that theClustersmodel and related algorithm provide a powerful simulation tool to design the isothermal or non-isothermal densification of devitrifying or stable glass compacts with any particle-size distribution, thus minimizing the number of time-consuming laboratory experiments. To cite this article: M.O. Prado, E.D. Zanotto, C. R. Chimie 5 (2002) 773?786© 2002 Académie des sciences / Éditions scientifiques et médicales Elsevier SASglass / non-isotherma