INVESTIGADORES
LOPEZ Beatriz Alicia
artículos
Título:
PARTICIÓN DE ELECTROLITOS 1:1 EN NITROBENCENO-AGUA
Autor/es:
T.SORIA; H.HERRERA; B. LÓPEZ,; H. MISHIMA,
Revista:
The Journal of the Argentine Chemical Society Anales de la Asociación Química Argentina
Editorial:
Asociación Química Argentina
Referencias:
Lugar: Buenos Aires; Año: 1986 vol. 74 p. 237 - 242
ISSN:
1852-1428
Resumen:
SUMMARY: Partíal AGp free energies of electrolytes 1:1 were determinadin the water-nitrobenzene system. Concentrations of the salts were determined at 25°C ± 0,1 from aliquots taken at of equilibrium phases. With the concentmtion valúes corrected through ionic association, the ionic partían constant, Ki, and the partition free energies AGp = RTLnKi were calculated. Comparíson between AG and free energies of transfer, AGt shows good accordance. This suggest that ions in the organic phase would be as non hydrated species.
