CONICET | Buscador de Institutos y Recursos Humanos

Silver nanoparticles (AgNPs) -stabilized by different sulfonated imidazolium salts (Lx)- have been synthesized as potential recyclable and reusable catalysts for the reduction of nitroaromaticcompounds in water. An exhaustive study of the catalytic activity is presented and kinetic data are explained in terms of the Langmuir?Hinshelwood model. The kinetic parameters and the performance of AgNP as catalysts were determined. The results reveal that catalysis is a superficialprocess and the reaction rate depends on the type of AgNP:Lx used as catalyst, with the imidazolium salts having the effects on the catalytic activity. The physicochemical and structuralcharacteristics of AgNPs are factors that influence the catalytic efficiency. The fact that these catalysts are recycled, in some cases for more than 6 cycles, opens a way for their recoveryand reuse of AgNPs. Finally, a comparative study with gold nanoparticles (AuNP) stabilized by the same salts has been realized.