INVESTIGADORES
FURLAN Ricardo Luis Eugenio
artículos
Título:
Molecular Amplification in a Dynamic System by Ammonium Cations
Autor/es:
FURLAN, RLE; NG, YF; COUSINS, GRL; REDMAN, JA; SANDERS, JKM
Revista:
TETRAHEDRON
Editorial:
Elsevier
Referencias:
Lugar: Oxford; Año: 2002 vol. 58 p. 771 - 778
ISSN:
0040-4020
Resumen:
Using hydrazone chemistry, a simple system of macrocyclic pseudo peptides was prepared which contains a cyclic structure thet resembles a known receptor for ammonium cations. A series of ammonium salts were tested as templates ant the expected receptor was amplified in different degrees according to the template used. Competitive non covalent interactions with a crown ether were used to demonstrate in situ that the template system is still dynamic.