INVESTIGADORES
DE MIGUEL Sergio Ruben
artículos
Título:
Estudio de Catalizadores de Rutenio para la obtención de Gas de Síntesis a partir del Reformado Seco de Metano
Autor/es:
SILVIA C.P. MAINA, SERGIO DE MIGUEL, OSVALDO A. SCELZA Y ESTANISLAO L. JABLONSKI
Revista:
REVISTA INFORMACION TECNOLOGICA DEL CHILE
Editorial:
CIT
Referencias:
Lugar: La Serena (Chile); Año: 2009 vol. 20 p. 21 - 28
ISSN:
0716-8756
Resumen:
This work studies the catalytic performance in dry reforming of Ru catalysts supported on gamma-Al2O3 promoted with Na, K, Mg, Ca and Ba. The supports and the catalysts were characterized and tested in the reaction of CH4 reforming with CO2. Ru/Al2O3-Na and Ru/Al2O3-K catalysts showed higher conversions and better H2/CO molar ratios. This catalytic behavior would be related with the higher metallic dispersions and with the basicity of the support. When the reduction time in H2 was shortened, a decrease of the conversions for all the catalysts, except for Ru/Al2O3-Na, was observed. This phenomenon would not be due to the thermal effect but to the reduction time.
