INVESTIGADORES
CHIAPPERO Malisa Susana
artículos
Título:
Novel synthesis of trifluoromethylnitrate, CF3ONO2
Autor/es:
M. S. CHIAPPERO, M. BURGOS PACI, TIMOTHY J. WALLINGTON Y GUSTAVO A. ARGÜELLO
Revista:
INORGANIC CHEMISTRY
Referencias:
Año: 2004 vol. 43 p. 2714 - 2716
ISSN:
0020-1669
Resumen:
Irradiation of the equilibrated gas mixture CF3O2NO2 / CF3O2 + NO2 at room temperature using the output from UV fluorescent blacklamps provides a rapid and simple method for the production of pure samples of CF3ONO2 in high yield (ca. 80%). This synthetic procedure is superior to that described in the literature in two aspects: (i) the yield of CF3ONO2 is approximately a factor of 5 greater, and (ii) the present method avoids the need for a high pressure (70 bar) reactor.
