Relaxation pathway confinement in glassy dynamics

J. A. RODRÍGUEZ FIRS; M. A. FRECHERO; G. A. APPIGNANESI

JOURNAL OF CHEMICAL PHYSICS

AMER INST PHYSICS

Lugar: American Institute of Physics; Año: 2014 vol. 141 p. 114905 - 114909

0021-9606

We compute for an archetypical glass-forming system the excess of particle mobility distributions over the corresponding distribution of dynamic propensity, a quantity that measures the tendency of the particles to be mobile and reflects the local structural constraints. This enables us to demonstrate that, on supercooling, the dynamical trajectory in search for a relaxation event must deal with an increasing confinement of relaxation pathways. This ?entropic funnel? of relaxation pathways built upon a restricted set of mobile particles is also made evident from the decay and further collapse of the associated Shannon entropy.