A particulate model of solid waste incineration in fluidized bed combining combustion and heavy metal vaporization

G. MAZZA, Q. FALCOZ, D. GAUTHIER AND G. FLAMANT

COMBUSTION AND FLAME

Elsevier Science

Lugar: Amsterdam; Año: 2009 vol. 156 p. 2084 - 2092

0010-2180

<!-- /* Font Definitions */ @font-face {font-family:SimSun; panose-1:2 1 6 0 3 1 1 1 1 1; mso-font-alt:宋体; mso-font-charset:134; mso-generic-font-family:auto; mso-font-pitch:variable; mso-font-signature:3 135135232 16 0 262145 0;} @font-face {font-family:"@SimSun"; panose-1:2 1 6 0 3 1 1 1 1 1; mso-font-charset:134; mso-generic-font-family:auto; mso-font-pitch:variable; mso-font-signature:3 135135232 16 0 262145 0;} /* Style Definitions */ p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-parent:""; margin:0cm; margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:12.0pt; font-family:"Times New Roman"; mso-fareast-font-family:SimSun;} p.MsoBodyText, li.MsoBodyText, div.MsoBodyText {margin-top:0cm; margin-right:0cm; margin-bottom:6.0pt; margin-left:0cm; mso-pagination:widow-orphan; font-size:12.0pt; font-family:"Times New Roman"; mso-fareast-font-family:SimSun;} p.MsoBodyTextFirstIndent, li.MsoBodyTextFirstIndent, div.MsoBodyTextFirstIndent {mso-style-parent:"Texto independiente"; margin-top:0cm; margin-right:0cm; margin-bottom:6.0pt; margin-left:0cm; text-indent:10.5pt; mso-pagination:widow-orphan; font-size:12.0pt; font-family:"Times New Roman"; mso-fareast-font-family:SimSun;} @page Section1 {size:612.0pt 792.0pt; margin:70.85pt 3.0cm 70.85pt 3.0cm; mso-header-margin:36.0pt; mso-footer-margin:36.0pt; mso-paper-source:0;} div.Section1 {page:Section1;} --> <!-- /* Font Definitions */ @font-face {font-family:SimSun; panose-1:2 1 6 0 3 1 1 1 1 1; mso-font-alt:宋体; mso-font-charset:134; mso-generic-font-family:auto; mso-font-pitch:variable; mso-font-signature:3 135135232 16 0 262145 0;} @font-face {font-family:"@SimSun"; panose-1:2 1 6 0 3 1 1 1 1 1; mso-font-charset:134; mso-generic-font-family:auto; mso-font-pitch:variable; mso-font-signature:3 135135232 16 0 262145 0;} /* Style Definitions */ p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-parent:""; margin:0cm; margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:12.0pt; mso-bidi-font-size:10.0pt; font-family:"Times New Roman"; mso-fareast-font-family:SimSun; mso-fareast-language:FR;} p.MsoBodyText, li.MsoBodyText, div.MsoBodyText {margin-top:0cm; margin-right:0cm; margin-bottom:6.0pt; margin-left:0cm; mso-pagination:widow-orphan; font-size:12.0pt; mso-bidi-font-size:10.0pt; font-family:"Times New Roman"; mso-fareast-font-family:SimSun; mso-fareast-language:FR;} p.MsoBodyTextFirstIndent, li.MsoBodyTextFirstIndent, div.MsoBodyTextFirstIndent {mso-style-parent:"Texto independiente"; margin-top:0cm; margin-right:0cm; margin-bottom:6.0pt; margin-left:0cm; text-indent:10.5pt; mso-pagination:widow-orphan; font-size:12.0pt; mso-bidi-font-size:10.0pt; font-family:"Times New Roman"; mso-fareast-font-family:SimSun; mso-fareast-language:FR;} @page Section1 {size:612.0pt 792.0pt; margin:70.85pt 3.0cm 70.85pt 3.0cm; mso-header-margin:36.0pt; mso-footer-margin:36.0pt; mso-paper-source:0;} div.Section1 {page:Section1;} --> <!-- /* Font Definitions */ @font-face {font-family:SimSun; panose-1:2 1 6 0 3 1 1 1 1 1; mso-font-alt:宋体; mso-font-charset:134; mso-generic-font-family:auto; mso-font-pitch:variable; mso-font-signature:3 135135232 16 0 262145 0;} @font-face {font-family:"@SimSun"; panose-1:2 1 6 0 3 1 1 1 1 1; mso-font-charset:134; mso-generic-font-family:auto; mso-font-pitch:variable; mso-font-signature:3 135135232 16 0 262145 0;} /* Style Definitions */ p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-parent:""; margin:0cm; margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:12.0pt; mso-bidi-font-size:10.0pt; font-family:"Times New Roman"; mso-fareast-font-family:SimSun; mso-fareast-language:FR;} p.MsoBodyText, li.MsoBodyText, div.MsoBodyText {margin-top:0cm; margin-right:0cm; margin-bottom:6.0pt; margin-left:0cm; mso-pagination:widow-orphan; font-size:12.0pt; mso-bidi-font-size:10.0pt; font-family:"Times New Roman"; mso-fareast-font-family:SimSun; mso-fareast-language:FR;} p.MsoBodyTextFirstIndent, li.MsoBodyTextFirstIndent, div.MsoBodyTextFirstIndent {mso-style-parent:"Texto independiente"; margin-top:0cm; margin-right:0cm; margin-bottom:6.0pt; margin-left:0cm; text-indent:10.5pt; mso-pagination:widow-orphan; font-size:12.0pt; mso-bidi-font-size:10.0pt; font-family:"Times New Roman"; mso-fareast-font-family:SimSun; mso-fareast-language:FR;} @page Section1 {size:612.0pt 792.0pt; margin:70.85pt 3.0cm 70.85pt 3.0cm; mso-header-margin:36.0pt; mso-footer-margin:36.0pt; mso-paper-source:0;} div.Section1 {page:Section1;} --> This study aims to develop a particulate model combining solid waste particle combustion and heavy metal vaporization from burning particles during municipal solid waste incineration in a fluidized bed. The original approach for this model combines an Asymptotic Combustion model for the carbonaceous solid combustion and a Shrinking Core model to describe the heavy metal vaporization phenomenon. A parametric study is presented. The global metal vaporization process is strongly influenced by temperature. Internal mass transfer controls the metal vaporization rate at low temperatures. At high temperatures, the chemical reactions associated with particle combustion control the metal vaporization rate. A comparison between the simulation results and experimental data obtained with a lab-scale fluid bed incinerator and Cd-spiked particles shows that the heavy metal vaporization is correctly predicted by the model. The predictions are better at higher temperatures because of the temperature gradient inside the particle. Future development of the model will take this into account.