Uracilato and 5-halouracilato derivatives of Cu(II), Zn(II) and Ni(II). X ray structures of [Cu(uracilato-N1)2(NH3)2]?(H2O), [Ni(5-chlorouracilato-N1)2(en)2]?2H2O and [Zn(5-chlorouracilato-N1)(NH3)3]?(5-chlorouracilato-N1)?(H2O)

TERRÓN A.; GARCÍA-RASO A.; FIOL J.J.; AMENGUAL S.; CALDENTEY F.; BARCELÓ-OLIVER M.; TÓTARO R. M.; APELLA M. C.

JOURNAL OF INORGANIC BIOCHEMISTRY

Elsevier

Lugar: New York; Año: 2004 vol. 98 p. 632 - 638

0162-0134

Four new complexes of uracilato and 5-halouracilato with the divalent metal ions Cu(II), Zn(II) and Ni(II) were obtained and structurally characterized. [Cu(uracilato- N1)2(NH3)2] 2(H2O) (1) and [Cu(5-chlorouracilato-N1)2(NH3)2](H2O)2 (2) complexes present distorted square planar co-ordination geometry around the metal ion. Although an additional axial water molecule is present [Cu(II)?OH2 ¼ 2.89 A (for 1) and 2.52 A (for 2)] in both cases, only in the complex 2 would be considered in the limit of a bond distance. The Zn(II) in [Zn(5-chlorouracilato-N1)(NH3)3] (5-chlorouracilato-N1) (H2O) presents a tetrahedral co-ordination with three ammonia molecules and the N1 of the corresponding uracilato moiety. A non-coordinated uracilato molecule is present as a counterion and a recognition between co-ordinated and free ligands, by means a tandem of H-bonds, should be mentioned. Finally, the complex [Ni(5-chlorouracilato-N1)2(en)2] (H2O)2 (where en is ethylenediamine) presents a typical octahedral trans coordination with additional hydrogen bonds between 5-chlorouracilato and the NH2 groups of ethylenediamine units.