IFEG 20353
INSTITUTO DE FISICA ENRIQUE GAVIOLA
Unidad Ejecutora - UE
artículos
Título:
Nd-Co substituted strontium hexaferrite powders with enhanced coercivity
Autor/es:
C. HERME; P. G. BERCOFF; S. E. JACOBO
Revista:
MATERIALS RESEARCH BULLETIN
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Año: 2012 vol. 47 p. 3881 - 3887
ISSN:
0025-5408
Resumen:
In this work we report the synthesis of Nd?Co substituted strontium hexaferrites of composition Sr1_xNdxFe11_xCoxO19 by the sol?gel auto-combustion method with further heat treatment. The analysis of the X-ray diffraction spectra shows the M-type hexagonal structure in samples treated at 1100 ºC for 2 h. Coercivity increases 11% with 0.2 Nd?Co substitution, reaching a value of 68.9 A/m (5480 Oe) while saturation magnetization is reduced 6% to 91 A m2/kg (91 emu/g). The behavior of magnetic susceptibility with an applied field shows two different maxima which are assigned to different magnetic orderings. This assumption is supported by the appearance of two experimental values of Curie temperatures (TC) for all the prepared samples. Magnetic susceptibility x and TC measurements suggest an uneven distribution of the iron vacancies.
