Angular distribution of H2 molecules scattered from the Pd(111) surface

DÍAZ, C.; BUSNENGO, H.F.; MARTÍN, F.; SALIN, A.

JOURNAL OF CHEMICAL PHYSICS

Año: 2003 vol. 118 p. 2886 - 2892

0021-9606

We study the scattering of H2 (v=0,J=0) molecules by the Pd(111) surface using classical trajectory methods. We show that the variation of the reflectivity with incidence angle can be explained with the combination of two processes: "dynamic trapping" and "direct dissociation" that verify total and normal energy scaling, respectively. The presence of the dissociation channel barely affects the angular distribution of scattered molecules. In the patterns of final angular distributions, the main difference, with respect to atom scattering, is a strong momentum transfer from motion normal to the surface toward molecular rotation.