Kinetic study of the combustion of ethanol, ethyl acetate and their mixture over a MnCu catalyst

MARÍA AGUSTINA CAMPESI; NÉSTOR JAVIER MARIANI; SERGIO PATRICIO BRESSA; MARÍA DEL CARMEN PRAMPARO; BIBIANA PATRICIA BARBERO; LUIS EDUARDO CADÚS; OSVALDO MIGUEL MARTÍNEZ; GUILLERMO FERNADO BARRETO

Congreso; 4th International Congress on Energy and Environment and Management; 2011

A kinetic study of ethanol and ethyl acetate combustion on an efficient catalyst identified as MnCu (9:1) is reported in this contribution. Ethanol and ethyl acetate are typical VOCs which can be found in effluents of printing industries. Ethanol oxidation produces an intermediate product, acetaldehyde. On the other hand, ethyl acetate oxidation produces directly CO2. Acetaldehyde reacts more slowly than ethanol, while ethyl acetate is slightly more difficult to oxidize than acetaldehyde. Strong inhibition effects among the species involved (ethanol, ethyl acetate and acetaldehyde) should be explicitly considered to propose reaction rate expressions. Thus, experimental data were satisfactorily fitted employing LHHW type expressions. The estimated activation energy of ethyl acetate and ethanol oxidation lies in the range of values reported in the literature for similar catalysts.