Effect of Melt Annealing on the Phase Structure and Rheological Behavior of Propylene-Ethylene Copolymers

VANESA DE LA TORRE; JORGE ARIEL RODRÍGUEZ FRIS; MARCELO DANIEL FAILLA; LIDIA MARÍA QUINZANI

POLYMER ENGINEERING AND SCIENCE

John Wiley and Sons

Lugar: Nueva York; Año: 2007 vol. 47 p. 912 - 921

0032-3888

The morphological and rheological properties of a commercial propylene-ethylene copolymer (PEC) and a series of blends with different concentrations of poly(ethylene-co-propylene) are investigated. The blends are prepared mixing PEC with fractions obtained from it by solvent extraction. The phase structure of samples exposed to different thermal and mechanical histories was analyzed using scanning electron microscopy. The linear viscoelastic properties of the molten polymers were measured using different test sequences that include dynamic frequency and time sweeps. The phase structure of most blends changes dramatically with time when the polymers are kept in the molten state due to the coalescence of the domains. For example, the initial morphology of PEC which presents domains of ~1 mm diameter changes to regions of more than 10 mm of average diameter after 90 minutes at 178°C at rest. Coincidentally, the dynamic moduli of the blends change during annealing reaching values that depend on the mechanical history. For example, the elastic modulus of PEC increases approximately 32% during a dynamic time sweep of 45 minutes using a frequency of 0.1 s-1, while it decreases ~18% when a frequency of 1 s-1 is applied. Moreover, the modulus measured at 0.1 s-1 of samples annealed at rest during 45 minutes is ~58% larger than that of the fresh material.