INQUIMAE 12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
congresos y reuniones científicas
Título:
Symmetry-directed photoinduced chemical reactions
Autor/es:
CADRANEL, ALEJANDRO; BARALDO, LUIS M.; OVIEDO, PAOLA S.; GULDI, DIRK M.; PIESLINGER, GERMAN E.
Lugar:
Newport
Reunión:
Conferencia; Gordon Research Conference on Electron Donor Acceptor Interactions; 2018
Resumen:
The metal-to-ligand charge transfer (MLCT) excited states of ruthenium polypyridines can be described as a combination of a reduced ligand and an oxidized metal center. In a {Ru(tpy)(bpy)} complex, the MLCT states bear a tpy?- radical anion and a Ru(III).What happens with the hole when the photoexcited metal center is electronically coupled with another metal center, as in photoinduced mixed valence systems?
