INQUIMAE 12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
Gaussian Distribution of Electron Transfer Distance in Redox Terminated Self-Assembled Thiol Monolayers
Autor/es:
HERRERA, S. ; DAVIA, F.; CALVO, E.J.
Revista:
JOURNAL OF PHYSICAL CHEMISTRY C
Editorial:
AMER CHEMICAL SOC
Referencias:
Lugar: washigton dc; Año: 2019 vol. 123 p. 13939 - 13943
ISSN:
1932-7447
Resumen:
A Gaussian distribution of tunneling distances due to different orientation populations in electrochemically active self-assembled monolayers composed of alkanethiols of different length has been assumed in a model which leads to a Gaussian distribution of the logarithm of the electron transfer constants. The model has been validated with experimental data for osmium terminated SAMs of different length using a modification of Creager?s method.
