Electrochemical impedance spectroscopy study of the LixMn2O4 interface with natural brine

WILLIAMS, FEDERICO J.; WILLIAMS, FEDERICO J.; MARCHINI, FLORENCIA; MARCHINI, FLORENCIA; CALVO, ERNESTO J.; CALVO, ERNESTO J.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY - (Print)

ELSEVIER SCIENCE SA

Año: 2018 vol. 819 p. 428 - 434

1572-6657

The LiMn2O4-Polypyrrole electrochemical cell has been shown to extract LiCl from natural brine at low voltage with high selectivity, low energy consumption (5?10 Wh·mol− 1) and good stability. The intercalation/de-intercalation of Li+ ions in LixMn2O4 (0 ≤ x ≤ 1) has been studied by electrochemical impedance spectroscopy (EIS) at different potentials and lithium ion concentrations using a modified Randles equivalent electrical circuit for the interface of LixMn2O4 in natural brine from Salar de Olaroz (Jujuy, Argentina). The RCT exhibits two minima at potentials which correspond to x = 0.25 and x = 0.75 (half filled adsorption sites) respectively and a linear lithium ion concentration dependence of (Li+)− 0.5 consistent with a lithium ion transfer adsorption model proposed by Bruce.