Recent Developments in Co III 2 Ln III 2 Single-Molecule Magnets

ALBORÉS, PABLO; FUNES, ALEJANDRO V.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

WILEY-V C H VERLAG GMBH

Año: 2018 vol. 20/1 p. 2067 - 2089

1434-1948

In this work we review the Co2IIILn2III family of compounds reported up to date that shows SMM features. The vast majority of them show a butterfly arrangement with LnIII ions placed at the body positions. The number of DyIII examples constitutes the majority, probably because of the intrinsic properties of this lanthanide ion regarding SMMs characteristics. Butterfly complexes have a SAP geometry around LnIII ions with a variety of distortion degrees. However, when looking at the key Ueff parameter trend through this family of complexes, itbecomes clear that a pure geometrical consideration is not enough to explain it. Ab initio based calculations provide evidence of highly anisotropic mJ ground states for complexes where LnIII = DyIII, pointing to exclusively mJ = 15/2 ground Kramers doublets. These calculations also agree with the thermally activated relaxation involving the first excited state and, in some examples where multiple relaxation pathways are observed, higher excited states. A few examples prove that Raman and/or direct mechanisms cannot be discarded a priori. Only two examples of isostructural LnIII families of the same Co2IIILn2III complex can be found.