INQUIMAE 12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
One dimensional Mn(III) Schiff-base complex organization through very strong symmetrical H-bond interaction
Autor/es:
LUCA CARRELLA; EVA RENTSCHLER; IRENE C. LAZZARINI; PABLO ALBORÉS
Revista:
INORGANICA CHIMICA ACTA
Editorial:
ELSEVIER SCIENCE SA
Referencias:
Lugar: Amsterdam; Año: 2016 vol. 453 p. 692 - 696
ISSN:
0020-1693
Resumen:
We are reporting the structural and magnetic characterization of a Mn(III) mononuclear complex based on a Schiff-base ligand with carboxylate pendant arm. Very strong symmetric H-interaction drives a one dimensional organization of thiscomplex, densely packed through C?H⋯π further interactions. Low temperature magnetic behaviour appears governed by local ion zero field splitting obscuring any possible weak exchange interaction through the symmetric H-bond pathway.
