INFIQC 05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
Visible light-promoted C?C bond formation from hydroxyaryls in water.
Autor/es:
RODRIGUEZ, S. A.; BAUMGARTNER, M. T; SAPORITO, D.
Revista:
AUSTRALIAN JOURNAL OF CHEMISTRY
Editorial:
CSIRO PUBLISHING
Referencias:
Lugar: Collingwood; Año: 2019 vol. 72 p. 978 - 982
ISSN:
0004-9425
Resumen:
An eco-friendly and direct arylation of hydroxyaryls in water using photoinduced reactions with different substrates (1-bromo-2-naphthol, 1-iodo-2-naphthol, N-(2-iodophenyl)acetamide, 5-bromouracil, 2-iodo-N-methylbenzamide, and 2-iodobenzamide) was studied. E.g. π-expanded coumarins, compounds with potential optical applications, were synthesized in very high yield, without the use of toxic reagents, in a one-pot reaction. In addition, we demonstrate that the irradiation source (halogen lamp) can be efficiently replaced by an LED without altering the reaction yield.
