Study of La4BaCu5−xCoxO13+δ series as potential cathode materials for intermediate-temperature solid oxide fuel cell

TELLEZ, JHOAN; CAPOEN, EDOUARD; NIEMCZYK, ANNA; SUESCUN, LEOPOLDO; TELLEZ, JHOAN; CAPOEN, EDOUARD; NIEMCZYK, ANNA; SUESCUN, LEOPOLDO; DURAN, SILVIA; MACIAS, MARIO A.; ROUSSEL, PASCAL; MOGNI, LILIANA; DURAN, SILVIA; MACIAS, MARIO A.; ROUSSEL, PASCAL; MOGNI, LILIANA; SANDOVAL, MÓNICA V.; PIROVANO, CAROLINE; BARRERA CASTILLO, MÓNICA; GAUTHIER, GILLES H.; SANDOVAL, MÓNICA V.; PIROVANO, CAROLINE; BARRERA CASTILLO, MÓNICA; GAUTHIER, GILLES H.

SOLID STATE IONICS

ELSEVIER SCIENCE BV

Año: 2018 vol. 326 p. 116 - 123

0167-2738

La4BaCu5−xCoxO13+δ system was successfully synthesized by a modified Pechini route in air. A structural phase transition is observed along the series, from tetragonal ordered structure for 0 ≤ x ≤ 2 to a rhombohedral disordered perovskite for x = 5. A TEC value of 17.3 × 10−6 K−1, was found by High-Temperature X-ray Diffraction (HT-XRD) in air for La4BaCu3Co2O13+δ. The conductivity of La4BaCu3Co2O13+δ increases with temperature reaching a maximum of 778 S cm−1 at 405 °C in air followed by a decrease with further increase in temperature with values of 600?664 S cm−1. The cathode polarization resistance of La4BaCu3Co2O13+δ evaluated in air at 750 °C is 0.34 Ω cm2 with an activation energy of 1.65 eV. These results demonstrate the possible use of La4BaCu5−xCoxO13+δ materials as cathode for Intermediate-Temperature Solid Oxide Fuel Cell (IT-SOFC).