INFIQC 05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
Photoinduced Electron-Transfer Cycloreversion of Thietanes: The Role of Ion−Molecule Complexes
Autor/es:
JUAN E. ARGÜELLO; RAÚL PÉREZ-RUIZ; MIGUEL A. MIRANDA
Revista:
ORGANIC LETTERS
Editorial:
AMER CHEMICAL SOC
Referencias:
Lugar: washington; Año: 2010 vol. 12 p. 1884 - 1887
ISSN:
1523-7060
Resumen:
Cycloreversion (CR) of thietane radical cations leads to formation of thiobenzophenone and the corresponding alkenes, eventually followed by secondary [4 + 2] cycloaddition. Final product distribution depends on the ability of fragments to escape from ion-molecule complexes (IMCs).
