INFIQC 05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
Quantitative Study of NonCovalent Interactions at the ElectrodeElectrolyte Interface Using Cyanide-Modified Pt(111) Electrodes
Autor/es:
MARÍA ESCUDERO ESCRIBANO; MARTÍN E. ZOLOFF MICHOFF; EZEQUIEL P. M. LEIVA; NENAD M. MARKOVIć; CLAUDIO GUTIÉRREZ; ÁNGEL CUESTA
Revista:
Chemphyschem
Editorial:
WILEY-V C H VERLAG GMBH
Referencias:
Año: 2011 vol. 12 p. 2230 - 2234
ISSN:
1439-4235
Resumen:
Cations at the OHP can interact through
noncovalent interactions with species at the IHP covalently bonded to the
electrode surface, affecting the structure and the properties of the
electrochemical double layer. These non-covalent interactions can be studied
quantitatively using cyanide-modified Pt(111) electrodes, and their effects
include a Nernstian-like dependence of the equilibrium potential on the
concentration of a species not involved in the electrochemical reaction.
