Polypropylene/clay nanocomposites produced by SCORIM: deformation and fracture properties

MARIA ALEJANDRA COSTANTINO; VALERIA PETTARIN; JULIO VIANA; ANTONIO PONTES; ANTONIO POUZADA; PATRICIA FRONTINI

STROJNISKI VESTNIK-JOURNAL OF MECHANICAL ENGINEERING

ASSOC MECHANICAL ENGINEERS TECHNICIANS SLOVENIA

Año: 2013 vol. 59 p. 697 - 704

0039-2480

The effect of distinct morphologies induced by shear controlled orientation in injection molding (SCORIM) in the mechanical and fracture performance of polypropylene (PP) and PP/nanoclay mouldings is examined in this work. The effect of high shear conditions applied during processing was assessed. Samples exhibited a range of fracture stability ranging from a modest non-linearity to a quasi-stable regime depending on material type and injection condition. Neat PP showed non-linear brittle behaviour while nanocomposites exhibited quasi-stable behaviour induced by the large deformation capability of the skin layer. Despite the fracture initiating at practically the same loading levels, the propagation energy varied with processing conditions and nanoclay content. The reduction of the core layer achieved by the SCORIM processing along with the differences between skin and core favoured by the presence of nanoclay are responsible of the toughening of SCORIM PP/nanoclay thick mouldings