Enhancing Hydrogen Evolution Activity of Au(111) in Alkaline Media through Molecular Engineering of a 2D Polymer

ABUFAGER, PAULA; VYAS, VIJAY S.; GUTZLER, RICO; LOMBARDI, JUAN MANUEL; GRUMELLI, DORIS; LOTSCH, BETTINA V.; LOMBARDI, JUAN MANUEL; GRUMELLI, DORIS; LOTSCH, BETTINA V.; ALEXA, PATRICK; BUSNENGO, HERIBERTO FABIO; HAASE, FREDERIK; KERN, KLAUS; ALEXA, PATRICK; BUSNENGO, HERIBERTO FABIO; HAASE, FREDERIK; KERN, KLAUS; ABUFAGER, PAULA; VYAS, VIJAY S.; GUTZLER, RICO

Angewandte Chemie

WILEY-V C H VERLAG GMBH

Lugar: Weinheim; Año: 2020 vol. 59 p. 8411 - 8415

1433-7851

The electrochemical splitting of water holds promise for the storage of energy produced intermittently by renewable energy sources. The evolution of hydrogen currently relies onthe use of platinum as a catalyst -which is scarce and expensive- and ongoing research is focused towards finding cheaper alternatives. In this context, 2D polymers grown as single layers on surfaces have emerged as porous materials with tunable chemical and electronic structures that can be used for improving the catalytic activity of metal surfaces. Here, we use designed organic molecules to fabricate covalent 2D architectures by an Ullmann-type coupling reaction on Au-(111). The polymer-patterned gold electrode exhibits a hydrogen evolution reaction activity up to three times higher than that of bare gold. Through rational design of the polymer onthe molecular level we engineered hydrogen evolution activity by an approach that can be easily extended to other electro-catalytic reactions.