INIFTA   05425
INSTITUTO DE INVESTIGACIONES FISICO-QUIMICAS TEORICAS Y APLICADAS
Unidad Ejecutora - UE
artículos
Título:
On the symmetry of four particles in a one-dimensional box with harmonic interaction
Autor/es:
FERNÁNDEZ, FRANCISCO M.
Revista:
JOURNAL OF MATHEMATICAL CHEMISTRY
Editorial:
SPRINGER
Referencias:
Año: 2018 vol. 56 p. 557 - 567
ISSN:
0259-9791
Resumen:
We show that a system of four particles in a one-dimensional box with a two-particle harmonic interaction can by described by means of the symmetry point group Oh. Group theory proves useful for the discussion of both the small-box and large-box regimes. We apply perturbation theory and obtain the corrections of first order for the lowest states. We carry out a simple Rayleigh?Ritz variational calculation with basis sets adapted to the symmetries of the system. We also obtain alternative variational results for the first three lowest energy levels that are more suitable for larger box sizes.