Silver Electrodeposition on Nanostructured Gold: From Nanodots to Nanoripples

P.C. DOS SANTOS CLARO, M. FONTICELLI, G. BENÍTEZ, O. AZZARONI, P. L. SCHILARDI, N.B. LUQUE+, E. LEIVA+ AND R.C. SALVAREZZA

NANOTECHNOLOGY

Año: 2006 vol. 17 p. 3428 - 3435

0957-4484

NOTA: todos los autores han contribuido de igual manera a la elaboración de este trabajo.Silver nanodots and nanoripples have been grown on nanocavity-patterned polycrystalline Au templates by controlled electrodeposition. The initial step is the growth of a first continuous Ag monolayer followed by preferential deposition at nanocavities. The Ag-coated nanocavities act as preferred sites for instantaneous nucleation and growth of the three-dimensional metallic centres. By controlling the amount of deposited Ag, dots of ∼50 nm average size and ∼4 nm average height can be grown with spatial and size distributions dictated by the template. The dots are in a metastable state. Further Ag deposition drives the dot surface structure to nanoripple formation. Results show that electrodeposition on nanopatterned electrodes can be used to prepare a high density of nanostructures with a narrow size distribution and spatial order.