IQUIR   05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Total Synthesis and Structural Validation of Phosdiecin A via Asymmetric Alcohol-Mediated Carbonyl Reductive Coupling
Autor/es:
DELLA-FELICE, F.; PILLI, R.A.*; SAROTTI, A.M.; KRISCHE, M. J.*
Revista:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Editorial:
AMER CHEMICAL SOC
Referencias:
Lugar: Washington; Año: 2019 vol. 141 p. 13778 - 13782
ISSN:
0002-7863
Resumen:
The first total synthesis and structural validation of phosdiecin A was accomplished in 13 steps through asymmetric iridium-catalyzed alcohol-mediatedcarbonyl reductive coupling. The present route is the shortest among >30 total and formal syntheses of fostriecin family members.