IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Very efficient and broad-in-scope palladium-catalyzed Hiyama crosscoupling. The role of water and copper(I) salts.
Autor/es:
TRAFICANTE, C. I.; MATA, E. G.; DELPICCOLO, C. M. L.
Revista:
RSC Advances
Editorial:
Royal Society of Chemistry
Referencias:
Lugar: Londres; Año: 2015 vol. 5 p. 26796 - 26800
ISSN:
2046-2069
Resumen:
A very high-yielding Pd-catalyzed cross-coupling between aryl halides and aryl(trialkoxy)silanes is achieved in the presence of Cu(I) and a measured amount of water. This novel methodology is useful for the generation of a wide range of biaryls, particularly non-para substituted derivatives, which are usually less reported.
