S=1/2 and S=1 Kondo Effect on Atomic Chains

L. COSTA RIBEIRO; I. J. HAMAD; G. CHIAPPE; E. V. ANDA

Paris

Conferencia; International Conference on Nanoscience and Technology ICN+T 2013; 2013

We analyze the transport properties of a double quantum dot device with both dots coupled to perfect conducting leads and to a finite chain of N non-interacting sites connecting both of them. The inter-dot chain strongly influences the transport across the system and the Local Density of States of the dots. We study the case of small number of sites, so that Kondo box effects are present, varying the coupling between the dots and the chain. For odd N and small coupling between the inter-dot chain and the dots, a state with two coexisting Kondo regimes develops: the bulk Kondo due to the quantum dots connected to leads and the one produced by the screening of the quantum dots spins by the spin in the finite chain at the Fermi level. As the coupling to the inter-dot chain increases, there is a crossover to a molecular Kondo effect, due to the screening of the molecule (formed by the finite chain and the quantum dots) spin by the leads. For even N the two-Kondo temperatures regime does not develop and the physics is dominated by the usual competition between Kondo and antiferromagnetism between the quantum dots. We finally study how the transport properties are affected as N is increased. For the study we used exact multi-configuration Lanczos calculations and finite U slave-boson mean-field theory at T = 0. The results obtained with both methods describe qualitativelyand also quantitatively the same physics.