Electrocatalytic Properties of a Novel Poly-1-Naphthylamine-Modified Electrode Using Ascorbic Acid as Molecule Probe

F. D'ERAMO*; L.E.SERENO; A.H.ARÉVALO

ELECTROANALYSIS

Wiley-VCH

Lugar: Alemania; Año: 2007 vol. 19 p. 96 - 102

1040-0397

A glassy carbon electrode was modified with an electropolymerized film of 1-naphthylamine in aqueous solution. The electrocatalitic properties of this modified electrode (ME) were investigated using ascorbic acid (AA) as probe molecule. The electrochemical behavior of AA in buffer solution was examined by voltammetry and amperometry. The results showed that the ME exhibited good electrocatalytic activity towards the oxidation of AA, as a consequence, it can be used as amperometric sensor of this analyte in a flow injection system with good sensitivity. Calibration curves were linear over the concentration range 0.05- 1.50 mM with a phosphate buffer solution pH 3 as the carrier, the detection limit was 1 ppm (S/R = 3). The methods were applied to the determination of AA in beverages and pharmaceutical products. A good correlation with a reference method was attained.