INVESTIGADORES
GERONES Mariana
artículos
Título:
Outermost and Inner-Shell Electronic Properties of ClC(O)SCH2CH3 Studied Using HeI Photoelectron Spectroscopy and Synchrotron Radiation
Autor/es:
L. R. PIRANI, M. F. ERBEN, M. GERONÉS, CHUNPING MA, M. GE,R. M. ROMANO, R. L. CAVASSO FILHO, Y C.O. DELLA VÉDOVA
Revista:
JOURNAL OF PHYSICAL CHEMISTRY A
Editorial:
AMER CHEMICAL SOC
Referencias:
Año: 2011 vol. 115 p. 5307 - 5318
ISSN:
1089-5639
Resumen:
A study of valence electronic properties of S-ethyl
chlorothioformate (S-ethyl chloromethanethioate), ClC(O)
SCH2CH3, using HeI photoelectron spectra (PES) and synchrotron
radiation is presented. Moreover, the photon impact
excitation and dissociation dynamics of ClC(O)SCH2CH32CH3, using HeI photoelectron spectra (PES) and synchrotron
radiation is presented. Moreover, the photon impact
excitation and dissociation dynamics of ClC(O)SCH2CH32CH3
excited at the S 2p and Cl 2p levels are elucidated by analyzing
the total ion yield (TIY) spectra and time-of-flight mass spectra
acquired in multicoincidence mode [photoelectronphotoion
coincidence (PEPICO) and photoelectronphotoionphotoion
coincidence (PEPIPICO)]. flight mass spectra
acquired in multicoincidence mode [photoelectronphotoion
coincidence (PEPICO) and photoelectronphotoionphotoion
coincidence (PEPIPICO)]. photoion
coincidence (PEPICO) and photoelectronphotoionphotoion
coincidence (PEPIPICO)]. photoionphotoion
coincidence (PEPIPICO)].