Graphical Representation of Analytical Data: Comparasión of different analysts using an acid-base titration and box plots

LUIS ESCUDERO; LUCIANO BUSTOS; SOLEDAD CERUTTI; LUIS D. MARTINEZ; JOSÉ A. GÁSQUEZ

The Chemical Educator

Elsevier B.V.

Año: 2009 vol. 95 p. 164 - 168

1430-4171

The statistical field of descriptive statistics involves the representation of experimental data sets in both numerical and graphical approaches. Concerning to graphical representations, there are a great variety of categorized graphs, which can often identify expected and unexpected effects in the data more quickly and, sometimes, "better" than any other data analysis method; histograms (frequency distribution diagram) and scatterplots are good examples of graphic presentations. There are other ways to visually inspect a data set besides histograms. One that is popular is the box-whisker plot. This type of plot shows the spread of the data in terms of the median, the medians of the upper and lower halves of the data, and the spread between the medians of the upper and lower halves. The medians of the upper and lower halves of the data set are called the upper and lower fourth, respectively. These medians, also called the hinges of the box plot, are then used to construct the box on the plot. Additionally, this type of plot is useful to carry out detection of outliers, comparisons between different methodologies, inter-laboratory analyses, and analysts, among others. In the present work, we used box plots as graphical representations to compare analytical data from acid-base titrations with two different indicators.