INVESTIGADORES
ALVAREZ Vera Alejandra
artículos
Título:
Preparation and Characterization of Polybutylene-Succinate/Poly(ethylene-glycol)/Cellulose Nanocrystals Ternary Composites
Autor/es:
L. LUDUEÑA; E. FORTUNATI; J. MORÁN; VERA ALVAREZ; V. CYRAS; DEBORA PUGLIA; L.B. MANFREDI; MARIANO PRACELLA
Revista:
JOURNAL OF APPLIED POLYMER SCIENCE
Editorial:
JOHN WILEY & SONS INC
Referencias:
Lugar: New York; Año: 2015
ISSN:
0021-8995
Resumen:
Ternary composites were prepared by twin screw extrusion from polybutylene-succinate (PBS), poly(ethylene-glycol) (PEG), and cellulose nanocrystals (CNC). The aim of the work is to improve the physical?mechanical properties of PBS by the addition of CNC. A PEG/CNC masterbatch was prepared in order to achieve a good dispersion of hydrophilic CNC in the hydrophobic PBS. The influence of the nanoparticle content on the polymer properties was studied. Regarding the thermal properties fractioned crystallization phenomena of PEG was observed during cooling from the melt. No significant nucleating effect of the nanocellulose was observed. The material containing 4 wt % of CNC showed the best mechanical performance among the nanocomposites studied due to the combination of high modulus and elongation at break with a low detrimental in strength compared with the PBS/PEG blend. Moreover, no nanocellulose agglomerations were observed in its FESEM micrograph