INVESTIGADORES
KAUFMAN Teodoro Saul
artículos
Título:
Alternate and Step-Economic Synthesis of the beta-Methylstyrene Chelating Pre-ligand of the Hoveyda-Grubbs? II Catalyst
Autor/es:
SIMONETTI, S. O.; LARGHI, E. L.; KAUFMAN, T. S.
Revista:
ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL
Editorial:
ROUTLEDGE JOURNALS, TAYLOR & FRANCIS LTD
Referencias:
Lugar: Londres; Año: 2015 vol. 47 p. 227 - 231
ISSN:
0030-4948
Resumen:
We have recently reported an efficient one-pot sequential homo-bimetallic catalytic propenylation of haloarenes with allyltri(n-butyl)tin under palladium catalysis and optimized the reaction conditions. As a further application of this novel strategy, with impact in fine chemistry, herein we report an alternate and convenient, step-economic synthesis of E-1-isopropoxy-2-propenylbenzene, the chelating pre-ligand of Hoveyda Grubbs II and related olefin metathesis catalysts, from commercial 2-halophenols.
