INVESTIGADORES
GRANADOS Alejandro Manuel
artículos
Título:
Unexpected formation of 1,3-diols from unsaturated chromium Fischer carbene complex and borane
Autor/es:
JOSÉ BARLUENGA; ALEJANDRO M. GRANADOS; FELIX RODRÍGUEZ; JEROME VADECARD; JAVIER F. FAÑANÁS
Revista:
TETRAHEDRON LETTERS
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Lugar: Amsterdam; Año: 1997 vol. 38 p. 6465 - 6466
ISSN:
0040-4039
Resumen:
ct,&unsaturated Fischer carbene complexesof chromium 1 react with borane-dimethyl sulfidecomplextogive,afteroxidationwithhydrogenperoxidearrdsodiumhydroxide.1.3-diols2 and variablemrrouutsof?alcohols3. Ttresameprocedureapplied10alkynylchromiumcarbenecomplex4 leadsto 3-hydroxyketone5
