INVESTIGADORES
TAVERNA PORRO Marisa Lia
artículos
Título:
Deacetylation of furanosides using banana as biocatalyst
Autor/es:
M. TAVERNA PORRO; J. M. MONTSERRAT; L. E. IGLESIAS; A.M. IRIBARREN
Revista:
JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC
Editorial:
Elsevier
Referencias:
Año: 2007 vol. 44 p. 138 - 143
ISSN:
1381-1177
Resumen:
The deacylation under hydrolytic conditions of methyl 2,3,5-tri-O-acetyl-alpha-d-ribofuranoside, methyl 2,3,5-tri-O-acetyl-beta-d-ribofuranoside, methyl 2,3,5-tri-O-acetyl-alpha,beta-d-arabinofuranosides and alkyl 2,3,5-tri-O-acetyl-alpha,beta -xylofuranosides have been studied using banana whole tissue as biocatalyst. Reaction regioselectivity strongly depends on substrate structure. Hydrolysis of methyl 2,3,5-tri-O-acetyl-alpha-d-ribofuranoside afforded methyl 2,3-di-O-acetyl-alpha-d-ribofuranoside in quantitative yield.
