INVESTIGADORES
OTERO Luis Alberto
artículos
Título:
Synthesis and Photovoltaic Applications of a 4,4 -Spirobi[cyclopenta-[2,1;b;3,4 b]dithiophene]-Bridged Donor/Acceptor Dye
Autor/es:
GIANLUCA POZZI; SIMONETTA ORLANDI; MARCO CAVAZZINI; DANIELA MINUDRI; LORENA MACOR; LUIS OTERO; FERNANDO FUNGO
Revista:
ORGANIC LETTERS
Editorial:
AMER CHEMICAL SOC
Referencias:
Lugar: Washington; Año: 2013 vol. 15 p. 4642 - 4645
ISSN:
1523-7060
Resumen:
A new donor/acceptor (D A) spiro dye (SCPDT1) featuring two bithiophene units, connected through an sp3 -hybridized carbon atom, was prepared by a multistep synthetic sequence involving the convenient assembly of the spiro system under mild catalytic conditions. The photocurrent spectrum of dye-sensitized solar cells incorporating SCPDT1 covers the spectral region ranging from 350 to 700 nm and reaches a wide maximum of ∼80% in the 420 560 nm range. Power conversion efficiencies of up to 6.02% were obtained.