Configurational Assignment of Epimeric Secondary Six-membered Allylic Alcohols by 13C Nuclear Magnetic Resonance Spectroscopy. A New Approach

TEODORO SAUL KAUFMAN; P MISCHNE, MIRTA; GONZALEZ SIERRA, MANUEL; A RÚVEDA, EMUNDO

CANADIAN JOURNAL OF CHEMISTRY

NATL RESEARCH COUNCIL CANADA-N R C RESEARCH PRESS

Lugar: Toronto; Año: 1986 vol. 64 p. 2331 - 2333

0008-4042

On the basis of the effects of the hydroxyl group on the 13C nuclear magnetic resonance chcmical shifts of thc allylic carhons, a new paramcter was defined and a new rule was proposed for the assignment of the stereochemislry of secondary six-membered allylic alcohols.