INVESTIGADORES
KAUFMAN Teodoro Saul
artículos
Título:
Synthesis and 13C Nuclear Magnetic Resonance Spectral Analysis of Some Terpenoids Related to the Cleistanthane Type Hydrocarbon Isolated from Amphibolis antartica
Autor/es:
TEODORO SAUL KAUFMAN; GONZÁLEZ SIERRA, MANUEL; A RÚVEDA, EDMUNDO; P MISCHNE, MIRTA
Revista:
CANADIAN JOURNAL OF CHEMISTRY
Editorial:
NATL RESEARCH COUNCIL CANADA-N R C RESEARCH PRESS
Referencias:
Lugar: Toronto; Año: 1987 vol. 65 p. 2024 - 2026
ISSN:
0008-4042
Resumen:
The
synthesis of the cleistanthane-type diterpene 13 (8-b(H), 14-b-ethyl,
13-methylene podocarpane), a dihydro epimer ofthe natural product 6, is
described. By comparison of the 13C nuclear magnetic resonance spectral data of
13 and related compounds with those reported for 6, the stereochemistry of the
C-14 side chain of the latter was confirmed.
