INVESTIGADORES
TAGLIAZUCCHI Mario Eugenio
artículos
Título:
Nonmonotonic diffusion of particles among larger attractive crowding spheres
Autor/es:
GREGORY PUTZEL; MARIO TAGLIAZUCCHI; IGAL SZLEIFER
Revista:
PHYSICAL REVIEW LETTERS
Editorial:
AMER PHYSICAL SOC
Referencias:
Lugar: New York; Año: 2014 vol. 113 p. 138302 - 138305
ISSN:
0031-9007
Resumen:
We study the diffusive motion of particles among
fixed spherical crowders. The diffusers interact with the crowders
through a combination of a hard-core repulsion and a short-range
attraction. The long-time effective diffusion
coefficient of the diffusers is found to depend nonmonotonically on the
strength of their attraction to the crowders. That is, for a given
concentration of crowders, a weak attraction to the crowders enhances diffusion.
We show that this counterintuitive fact can be understood in terms of
the mesoscopic excess chemical potential landscape experienced by the
diffuser. The roughness of this excess chemical potential landscape
quantitatively captures the nonmonotonic dependence of the diffusion
rate on the strength of crowder-diffuser attraction; thus, it is a
purely static predictor of dynamic behavior. The mesoscopic view given
here provides a unified explanation for enhanced diffusion effects that have been found in various systems of technological and biological interest.