COMPARATIVE STUDY OF Ag NANOPARTICLES INCORPORATION IN TiO2 COATINGS BY DOPING AND IMPREGNATION TECHNIQUES.

ROLDÁN V.; DE OÑA P.; PELLEGRI N.; GRAU R.

Anales AFA

Asociación Física Argentina

Lugar: Tandil; Año: 2012 vol. 24 p. 64 - 70

0327-358X

In the present study, Ag NPs have been synthesized by colloidal process and incorporated into SiO2 and TiO2 coatings by doping of sol-gel precursors. In other technique, SiO2 and TiO2 films were impregned by Ag+ ions and then they were photoreduced. Ag nanoparticles characterization was carried out through Transmission Electron Microscopy (TEM), Grazing X-ray diffraction (GXRD) and UV- visible spectroscopy before and after being combined with the different sols, observing that the oxidation state of Ag NPs depends on the environment. Coatings doped with Ag nanoparticles were also prepared with hierarchical structures built by combining the different composition and analysed by TEM, GXRD and photocatalytic degradation of methyl orange. High photocatalytic efficiency was observed under UV illumination. The key factor in the photocatalytic efficiency of the multilayer coating systems resides in the metallic state of Ag NPs that could reduce the recombination of photo-generated electrons and holes thus increasing the transfer efficiency of the charge carriers. The best efficiency was obtained for SiO2/Ag-TiO2 dense and mesoporous impregnated and Ag-SiO2/TiO2 mesoporous system with a percentage of degradation 36 % higher than the reference of non-doped systems. Finally, bactericide assays were performed, showing a strong bactericide activity over the three strains tested, remarkably increased for all the samples doped with Ag. Key Word: photocatalysis, bactericide, titania, metal nanoparticles